In this book, for the first time we introduce the notions of Ngroups, N-semigroups, N-loops and N-groupoids. We also define a mixed N-algebraic structure. We expect the reader to be well versed in group theory and have at least basic knowledge about Smarandache groupoids, Smarandache loops, Smarandache semigroups and bialgebraic structures and Smarandache bialgebraic structures.